Optical basicity

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August undefined, 2024

WebThe study of polarizability, optical basicity, and electric susceptibility carried out on the new and very rare set of bismuth - tellurite glasses doped with Ho 3+ ions were fabricated by the conventional melt quenching process. The non-crystalline nature was confirmed by X-ray diffractometer measurements. Physical properties such as rare earth ... WebDec 20, 2024 · Titanium-doped and titanium-free lithium borate glasses were prepared using a quenching method and high-purity-grade chemical substances. Structural analysis was carried out by Fourier transform infrared (FT-IR) spectroscopy and mechanical measurement. The states of the produced glasses were examined by x-ray diffraction, and …

Optical basicity and refractivity of aluminosilicate glasses

WebFeb 25, 2002 · The optical basicity for La 2 O 3 oxide is found to be 1.07, being much larger compared with typical glass-forming oxides such as B 2 O 3 (0.42) and SiO 2 (0.48) but being similar to heavy element oxides such as TeO 2 (0.93). WebApr 8, 2024 · Physical properties were studied such as; X-ray diffraction, FTIR spectra, and UV–visible transmission. The optical basicity, average electro negativity have been estimated. The estimated... c sharp input

Basicity, Electronegativity, Optical Parameters and Radiation ...

WebDec 2, 2014 · Optical basicity depends on the electronegativity of the ions of an individual oxide. This feature represents the bonding characteristics, ionization ability, ion size, and consequently the mobility of free ions inside the slag. These properties affect the electrical conductivity of slags. WebJan 1, 2024 · The optical basicity of prepared glasses decreased with the increasing concentration of lanthanum oxide. Metallization criterion on the basis of refractive index … WebTo account for selectivity as a general concept that allows the classiﬁcation of reactions, it would be necessary to have available parameters accounting for a similar type of … csharp input

Estimation Model for Electrical Conductivity of Molten CaF

How to calculate optical basicity of oxides? ResearchGate

WebMar 13, 2024 · A brief study on optical and mechanical properties of an organic material: Urea glutaric acid (2/1)-a third order nonlinear optical single crystal. Crystals 2024, 11, 1239. [Google Scholar] Dimitrov, V.; Sakka, S. Electronic oxide polarizability and optical basicity of simple oxides. J. Appl. Phys. 1996, 79, 1736–1740. WebThe gamma and A values allow the basicity of a glass composed of these oxides to be expressed numerically on the optical basicity scale. Data that are available for phosphate glasses include all the rare earth ions (except Pm3+) and indicate a very irregular trend in gamma, but with an overall increase from La3+ to Lu3+ (which has gamma=1.03 ... eacts kongressWebMay 19, 2004 · The optical basicity treatment of oxidic network systems, for example silicates, has been successful in correlating a range of properties; since the method has the advantage of avoiding such problems as those associated with “single ion” activities, it allows comparisons between many different systems. However, several of the properties … eacts trading

"WebNov 28, 2024 · The experimental results show that LS significantly increases with the increase of temperature, basicity, and Na2O content, whereas it decreases with the … " - Optical basicity

Optical basicity

WebApr 28, 2024 · The optical basicity follows the same trend as the electronic polarizability, which can be attributed to the more acidic nature of P 2 O 3 compared with TiO 2. Moreover, the decrease of the optical basicity with increasing TiO 2 content supports the low ability of TiO 2 compared with P 2 O 5 to transfer electrons to the surrounding cations.

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WebApr 12, 2024 · The present research provided excellent dispersion of a thin film composite membrane with high power density, excellent long-term performance stability, and good mechanical durability for salinity gradient energy generation. Sulfonated polymers and graphene nanosheets provide an essential platform for the development cost-effective … WebFeb 25, 2002 · The electronic polarizability and optical basicity of La 2 O 3 and related glasses have been determined from ultraviolet absorption spectra and calculations based …

WebApr 12, 2024 · Few reports exist on the effect of the basicity of refining slag on inclusions in 15-5PH stainless steel and its removal efficiency. In this study, the effects of various basicities on the formation and removal efficiency of inclusions in molten steel were investigated. To investigate the effect of the chemical makeup of slag on the non-metallic … WebJan 1, 2024 · The optical basicity of prepared glasses decreased with the increasing concentration of lanthanum oxide. Metallization criterion on the basis of refractive index showed an increasing trend while energy band gap based metallization criterion showed a decreasing trend.

WebJul 17, 2024 · The optical basicity of present glasses are also estimated. Moreover, we studied many desirable features such as density, molar volume, oxygen packing density and the average phosphorus–phosphorus distance. WebThe optical basicity of complex nitrides can therefore be calculated by the same method established for oxides using the equivalent fractions and the basicity of the constituent …

WebAug 1, 2024 · Optical bandgap energy, refractive index, molar polarizability, molar electronic polarizability, electronic polarizability, and bandgap based oxide ion polarizabilities, optical basicity, electric susceptibility, and other important parameter were reported in this work.

WebAug 13, 2002 · The acid−base properties of germanate glasses cannot presently be compared quantitatively with those of silicate, borate, and several other glasses because the optical basicity of the parent oxide, Λ(GeO2), has not yet been unequivocally established. The usual method of measuring optical basicity, relying on probe ions such as Tl+ or … csharp int32WebOct 5, 2009 · The results showed that an increase of the calculated optical basicity was related to an increased number of bubbles in the glass samples. The oxygen activity in the melt during fining decreased with increased optical basicity. Document Type: Research Article. Publication date: 01 October 2009. eacts mcsWebJun 7, 2024 · The main reason is that the optical basicity of transition metal oxides cannot be directly measured because the own d orbitals of cations are involved and because their metal-oxygen bonds have an... eacts mcs berlinWebOct 10, 2024 · Optical basicity is identified as the average electron donor power of a fluorinated or oxidic compound (Herrmann et al., 2015). For a glass system consisting of … csharp initialize string arrayWebFeb 1, 2024 · The concept of optical basicity (Λ) is particularly suited to binary oxides and oxidic network materials such as silicates to characterize the acid–base nature of glasses … csharp inputboxWebAug 9, 2024 · The Figure S1b presents the optical basicity behavior for SixMg, SixCa, SixNNa, and SixNLiNa glasses in a higher magnification. The optical basicity is found for all silicate glasses to increase approximately linearly with total modifier content, while pyrophosphate glasses appear to partially deviate from this trend. eacts mailandWebFeb 13, 2024 · However, whilst optical basicity can provide useful empirical correlations (e.g. sulphide capacity of ladle slags ), these values have not been successfully linked to … c sharp insert into array